Thermodynamic Properties of Rare Earth Complexes. XIV. Free Energy, Enthalpy and Entropy Changes for the Formation of Lanthanoid Malonate and Hydrogen Malonate Complexes.
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چکیده
منابع مشابه
2,3-Diaminopyridinium hydrogen malonate
In the title mol-ecular salt, C5H8N3(+)·C3H3O4(-), the cation is essentially planar, with a maximum deviation of 0.005 (1) Å for all non-H atoms. In the anion, an intra-molecular O-H⋯O hydrogen bond generates an S(6) ring. In the crystal, the cations and anions are connected via N-H⋯O hydrogen bonds and a weak C-H⋯O inter-action, forming layers parallel to the ab plane.
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3,4-Diaminopyridinium hydrogen malonate
In the title salt, C5H8N3 (+)·C3H3O4 (-), the 3,4-di-amino-pyridinium cation is almost planar, with an r.m.s. deviation of 0.02 Å. The conformation of the hydrogen malonate anion is stabilized by an intra-molecular O-H⋯O hydrogen bond, which generates an S(6) ring. In the crystal, N-H⋯O hydrogen bonds link cations and anions into layers parallel to the ab plane.
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ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1973
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.27-0733